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MSE course syllabi

Materials Science and Engineering 735

Corrosion Science

 

Description:

Theories and mechanisms of corrosion.

Level & Credits:

G, 3 cr hrs

Prerequisites:

Graduate standing in MSE; Thermodynamics, Structure, property, and chemistry of materials, Simple electrical circuits, and Elementary electrochemistry

Objective:

Detailed understanding of principles behind the corrosion of metals, and methods for prevention, control, and experimentation.

Text:

D. A. Jones, Principles and Prevention of Corrosion, 2nd Ed., Prentice Hall, 1996.

Grading:

2 Exams 67%

1 Term Paper 33%

Homework will be assigned but not graded

Topics/Structure:

  1. Electrochemical basis of corrosion
  2. Structure of electrochemical interface
  3. Thermodynamics and Nernst Eqn.
  4. Kinetics of corrosion, polarization
  5. Passivity and localized corrosion
  6. Alloy corrosion and dealloying
  7. Corrosion protection
  8. Experimental methods
  9. Environmental cracking
  10. Atmospheric corrosion, oxidation

Week

Materials to Be Covered

Book Section*

1

Introduction, forms of corrosion
Basic electrochemistry
Potential, interface structure
Thermo

J: 1.1-1.5, F: 1.1
B: Ch 2, 4
S: Ch 20, B: Ch 7
J: 2.1.1-2.1.2, F: 1.2

2

Film, Corrosion in Action
Nernst equation
Reference electrodes
Pourbaix diagrams

J: 2.1.3-2.1.4
J: 2.3.1
J: 2.2

3

Kinetics - activation polarization
Butler-Volmer, Tafel eqns
Hydrogen Evolution Reaction

J: 3.1-3.2.1, F: 1.3
B: Ch 8
B: Ch 10

4

Mixed potential theory
Galvanic corrosion
DC measurement techniques
Concentration polarization
Ohmic resistance effects

J: 3.3
J: 6
J: 2.3, 3.4, F: 1.3, 7
J: 3.2.2, 3.3.4, B: Ch 1, Mar: Ch 1, F: 1.4
J: 3.5.4, F: 1.3

5

Exam 1
Polarization resistance

J: 5.2- 5.5, F: 1.3, 7

6

EIS
Laboratory session

J: 3.5.6, 5.6.3, F: 7

7

Passivity, stainless steel
Pitting corrosion
Crevice corrosion

J: 4, Mar: Ch 5-7
J: 7, Mar: Ch 8-10
J: 7, Mar: Ch 11

8

Intergranular corrosion
Coatings, Inhibitors
Alloy dissolution
Embrittlement

J: 9.1.1-9.1.4
J: 14, Mans: Ch 3, 4
J: 9.5, Mans: Ch 2
J: 8, 10.1, Mar: Ch 12, 13
Mans: Ch 10,11

9

Atmospheric corrosion
High temperature oxidation
Cathodic Protection
Corrosion in concrete
Microbially induced corrosion

J: 12, Mar: Ch 15
J: 12
J: 13
J: 11.5J: 11.3

10

Exam 2
Oral presentations**

*Key: J - Jones, F - Frankel, B - Bockris, S - Shreir, Mans - Mansfeld, Mar - Marcus

**Depending on availability of time.

Academic Integrity, Academic Misconduct

Academic misconduct may be found in any action that tends to distort the accurate assessment of any student’s individual accomplishments that are evaluated for the purpose of grading or conferring academic credit. Note that a student may be guilty of academic misconduct, for example, by cheating, collaborating, plagiarizing, or by allowing another student to cheat, collaborate, or plagiarize. Note also that the distortion applies, for example, to exams, homework assignments, and laboratory work. To the extent that any class activity (for example: attendance or participation) is used for evaluation for the purpose of grading or conferring academic credit, falsifying or distorting such activity, or permitting another student to falsify or distort such activity, represents academic misconduct.

Additional guidance about what represents academic integrity and misconduct, and related university-wide policies and procedures are available at the following locations:

http://oaa.osu.edu/coam/faq.html

http://oaa.osu.edu/coam/ten-suggestions.html

Course-specific exceptions or amplifications to the departmental and university statements outlined above will be provided by the faculty instructor in writing, preferably as part of the course syllabus.

Note: Students should not request nor accept guidance on these matters from a teaching assistant, fellow student, or anyone other than the faculty instructor of record for this course.

Disabilities Statement

Any student who feels s/he may need an accommodation based on the impact of a disability should contact the Office for Disability Services at 614-292-3307 in room 150 Pomerene Hall to coordinate reasonable accommodations for students with documented disabilities. (URL: http://www.ods.ohio-state.edu/)

Advice on such matters is also available from the MSE department’s undergraduate adviser (1xx-6xx courses) and graduate coordinator (7xx-9xx courses) whose offices may be found in room 477 Watts Hall.

Megan Daniels, Undergraduate Advisor, (614) 292-3145, e-mail Megan concerning the MSE undergrad studies

Mark Cooper, Graduate Studies Coordinator, (614) 292-7280, e-mail Mark concerning the MSE graduate studies