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MSE course syllabi

Materials Science and Engineering 662

Corrosion

 

Catalog Data:

Principles of corrosion engineering; definitions, types of corrosive attack, and methods of minimization and prevention. Au. Qtr. Elective.

Prerequisites:

4th year standing in engineering or permission of instructor.

Time Distribution:

2-48 minute lectures per week

1-1hr 48 min lab session per week.

Objectives:

Understanding of the basic principles behind the corrosion of metals, and methods for corrosion prevention, control, and experimentation. Meet ABET Criteria 3 Outcomes a, b, e, g, h, and k.

Textbooks:

D.A. Jones, Principles and Prevention of Corrosion, 2nd, Ed. Prentice Hall, 1995.

Other supplemental reading will be provided.

Lecture Topics :

Each bulleted item comprises approximately one lecture

  • Corrosion: metals and the environment, Cost of Corrosion, Corrosion as an electrochemical process.
  • Important electrochemical reactions in corrosion processes, An overview of the forms of corrosion.
  • Corrosion as a "cell reaction", Faraday’s law and related corrosion rate expressions, Corrosion rate expressed as current and current density, Corrosion rate expressions for corrosion engineering, Conversion among expressions for corrosion rates.
  • Free energy change and electrode potentials, Standard electrode potentials, Computing corrosion cell potentials, The Golden Rules of corrosion thermodynamics, Measuring electrode potential.
  • Concentration effects on cell potential--the Nernst equation, Important reduction reactions for corrosion processes and the Nernst equation, A brief introduction to corrosion potentials.
  • Graphical representation of electrochemical equilibria – Pourbaix Diagrams.
  • Interpretation of Pourbaix Diagrams.
  • Exchange current density, Evans diagrams.
  • Activation polarization, Concentration polarization, Combined polarization.
  • Mixed Potential Theory, Evans Diagrams, Passivity.
  • Intergranular corrosion of stainless steels, Intergranular corrosion of Al alloys, Intergranular corrosion due to welding.
  • Measurement of polarization curves, Measurement of Corrosion Rate: Tafel extrapolation, Polarization resistance.
  • Sources of error in polarization resistance measurements.
  • Galvanic corrosion.
  • Pitting, Crevice Corrosion.
  • Environment assisted cracking, Stress corrosion cracking.
  • Hydrogen assisted cracking of metals, Other forms of hydrogen damage.
  • An over view of fatigue, Fractographic characterization, Graphical representations of fatigue data, Corrosion fatigue, Non-fracture mechanics approaches to characterization of corrosion fatigue.
  • Erosion Corrosion, Dealloying.
  • Anodic protection, Cathodic protection.
  • Inhibitors, Coatings.

Lab Exercises:

Potential Measurement

Intergranular corrosion

Polarization and passivity

Galvanic Corrosion

Pitting

Grading Plan:

20% homework (~4 assignments), 20% midterm (1), 25% final (1).

35% lab (5 lab write-ups and presentation; no formal lab reports).

Professional Component Content:

Engineering Science: 2.5 credits or 83%.

Engineering Design: 0.5 credits or 17%.

Design Component Content:

In lectures students learn the principles of design for corrosion resistance. In lab exercises, students must understand the fundamentals of experimental design to isolate variables and determine their influence on material response

Relation to Program Objectives:

1. This course covers the fundamental concepts in corrosion science and engineering.

2. Students have the opportunity to exercise fundamental concepts in structured laboratory exercises that parallel lecture material.

3. Students have the opportunity to understand the relationships between processing, resulting microstructure, and corrosion susceptibility of metals and alloys.

4. This course prepares students for graduate research and employment in the area of materials design, engineering design, and corrosion science and engineering.

Academic Integrity, Academic Misconduct

Academic misconduct may be found in any action that tends to distort the accurate assessment of any student’s individual accomplishments that are evaluated for the purpose of grading or conferring academic credit. Note that a student may be guilty of academic misconduct, for example, by cheating, collaborating, plagiarizing, or by allowing another student to cheat, collaborate, or plagiarize. Note also that the distortion applies, for example, to exams, homework assignments, and laboratory work. To the extent that any class activity (for example: attendance or participation) is used for evaluation for the purpose of grading or conferring academic credit, falsifying or distorting such activity, or permitting another student to falsify or distort such activity, represents academic misconduct.

Additional guidance about what represents academic integrity and misconduct, and related university-wide policies and procedures are available at the following locations:

http://oaa.osu.edu/coam/faq.html

http://oaa.osu.edu/coam/ten-suggestions.html

Course-specific exceptions or amplifications to the departmental and university statements outlined above will be provided by the faculty instructor in writing, preferably as part of the course syllabus.

Note: Students should not request nor accept guidance on these matters from a teaching assistant, fellow student, or anyone other than the faculty instructor of record for this course.

Disabilities Statement

Any student who feels s/he may need an accommodation based on the impact of a disability should contact the Office for Disability Services at 614-292-3307 in room 150 Pomerene Hall to coordinate reasonable accommodations for students with documented disabilities. (URL: http://www.ods.ohio-state.edu/)

Advice on such matters is also available from the MSE department’s undergraduate adviser (1xx-6xx courses) and graduate coordinator (7xx-9xx courses) whose offices may be found in room 477 Watts Hall.

Megan Daniels, Undergraduate Advisor, (614) 292-3145, e-mail Megan concerning the MSE undergrad studies

Mark Cooper, Graduate Studies Coordinator, (614) 292-7280, e-mail Mark concerning the MSE graduate studies